kwilliams,
.net introduces a new namespace (System.IO)
Here is a link to the MSDN http://msdn2.microsoft.com/en-gb/library/system.io.aspx
This is not to say that you can not use FSO (i have not tried but i assume it still works). As well i believe there is another namespace other than System.IO that you can use but (i believe) System.IO is the preferred method. As least this is what i have been using.
I just put this together so it may work and it may not work. Youll have to change the variables in the File.Copy method as those are just telling you what it needs.
If you have any problems post back but also do a google on System.IO and youll get some hits.
Imports System.IO
Dim strPhotoPath = Trim(rsPhoto("DC_FileName").Value.ToString)
Dim strPhotoFilePath As String = "\\SERVER1\Photo\" & strPhotoPath
Dim strPhotoDestination As String = "e:\wwwroot\SERVER2\temp\"
If File.Exists(strPhotoFilePath) Then
File.Copy(SourceFileName, DestFileName)
End If